Well…
With a DCC system a multimeter is useful, but doesn’t always give you the answer you expect.
To check track voltage on a DCC layout, select the AC setting, and probe across the rails. The number won’t be “right” because the meter is calibrated expecting AC to be a sine wave, but you should at least get a reading, if there is power to the rails, of something between 10 and 15 Volts. So it can tell you that there is voltage there.
You need to be realy careful trying to measure current, a lot of meters on measure fairly small currents, and you will blow a fuse if you try to measure more. Or if you put the probes across the voltage source, and create a short through the meter, for that matter. To measure current the meter needs to be in series with the circuit, which means you have to break the circuit, and insert the meter.
Tony’s Trains sells a product called a RRampMeter, which is a much better tool for taking DCC measurements.
A DCC system with a 5A booster can put out up to 5A. The amount of current (Amps) is dependent on how much is being drawn, not on the supply, up to that limit. In other words, with no locos on the rails, the draw will be zero, each operating loco could add a quarter of an amp, or so, often quite a bit less.
The most useful function of the multimeter is the Ohmeter function, which you can use to check for shorts, and continuity. With the booster disconnected, you can make sure everthing that is supposed to be connected is, and everything that isn’t supposed to be connected isn’t.