Rob,
PRR steam engines were painted Brunswick Green (known officially as Dark Green Locomotive Enamel, or DGLE), a shade of green so black it may as well have been black. From Jerry Britton’s Keystone Crossings website (http://kc.pennsyrr.com) we have two suggestions:
“Testors Enamels: to a new bottle of Black, add 1 bee bee and Brunswick Green paint to the top, mix well.” – Greg Martin
“Polyscale: DGLE is okay, but a represents an oxidized, weathered color. Add steam locomotive black for a newer look.” – Bruce Smith.
Tender decks and slope sheets were often (but not always – this was inconsistently applied) Freight Car Color (FCC), which from the same site is given as:
“Freight Car Color 1930’s - 1 part (50%) Poly Scale Zinc Chromate Primer to 1 part (50%) SAL Orange – Bob Johnson PRRT&HS Paint Committee”
“Freight Car Color 1930’s - 4 parts Scalecoat Illinois Central Orange to 1 part Oxide Red – Bruce Smith PRRT&HS Paint Committee”
“Freight Car Color 1940’s - 2 parts (66%) Poly Scale Zinc Chromate Primer to 1 part (33%) SAL Orange – Bob Johnson”
“Freight Car Color 1940’s - 50% Poly Scale Special Oxide Red to 50% Zinc Chromate Primer – Bruce Smith”
“Freight Car Color 1950’s - 100% Poly Scale Zinc Chromate Primer – Bob Johnson
PRRT&HS Paint Committee also: Greg Martin”
“Freight Car Color 1950’s - Elden Gatewood PRRT&HS Paint Committee also: Douglas Nelson”
The cab roof was painted with a mix of black and FCC which varied from shop to shop. Generally, the cab roof should be several shades darker (up to 50%) than the tender deck.
It should be noted that while all locomotove classes (except switchers such as the A5 and B6 classes) may have received this paint (red roof and tender deck) up to World War Two, after WWII it was sort of a crap shoot.