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From the photos you posted it appears that there are plates that hold the couplers in place.
I would begin by cutting off the existing Hook & Horn coupler- -since you are replacing it anyway- -to give you better working room.
With a jewelers file, try filing down the shoulders of the rivets flush with the plates holding the couplers in place.
Then carefully pry off the gearbox (coupler pocket) plates.
If you file the shoulder of the rivet flush with the gearbox plate and it still doesn’t budge- -by hand- -use a drill bit the same size as the hole, and carefully remove the last part of the rivet.
By the looks of the coupler pockets you might not be able to use a Kadee #5.
Kadee 30 series might fit your situation better.
After removing the rivet you will need to drill and tap the frame for a 2-56 screw. Kadee has a kit to do this.
Then I would use their #256 nylon screw, cut to length, to mount the new coupler assembly.
If you want to use a #5 or whisker-type coupler, I would definitely use a gearbox to insulate the metal frame from the metal coupler- -which could cause electrical problems.
You will need to remove material from the existing coupler pocket.
That’s why I recommend the 30 series couplers, which won’t require opening up the coupler pocket.
Use a #206 Kadee coupler height gauge to make sure that the new couplers are at the proper height.
Keep us updated on your progress and…
Hope this helps.