Hi, Charles
If you are just starting out with airbrushing and taking that leap from the 97¢ Sam’s Choice rattle can may I suggest getting a decent book on the subject.
Our very own Cody Grivno has an excellent book covering work shop tips including airbrushing.
https://kalmbachhobbystore.com/product/book/12475
The choice of paint will, to some degree, be a choice that only you can answer but you have to give the various types a test drive for yourself. Each one has advantages and each one has disadvantages.
For years I was spoiled by the acrylic, water-cleanup paints. Yes, they were nearly all flat finish so an additional gloss coat had to be applied if you were using decals. (I use dry transfers on some of my models, which do not require a glossy surface)
When Polly S and Modelfllex dried up I started looking for alternatives and decided to give Scalecoat a try. Weaver Models formerly distributed the paint and they had some tips for using it on their site.
I gave you the link to the new distributor above but the tips/hints page is no longer there.
Shooting enamel or lacquer paints requires different air and nozzle settings than with acrylic paints.
Scalecoat I is formulated for shooting directly on bare (clean) brass, metal or wood and Scalecoat II is formulated to spray directly on bare clean plastic.
Both dry to a hard, high gloss surface that, I have found, is ideal to apply decals to directly. None of my painting sessions with Scalecoat have ever required a second coat (unless doing a multi-color job, of course)
I do like to bake BRASS models, with ALL plastics removed (NO motors, wiring, plastic details) at about 150-170° F for about 45 min-1hr. (exact conditions may vary and this step is recommended but OPTIONAL) I check the oven with an IR thermometer.
Below is a link so you can browse Cody’s Magnum Opus before in